Synthesis and Physical Properties of Novel 7, 12-Diaryl-<i>N</i>-phenylbenzo[<i>k</i>]fluoranthene-9, 10-dicarbox- imides

Yuki Nakahara; Haruki Shimosasa; Ryuta Miyatake; Naoki Kobayashi; Mitsunori Oda

doi:doi:10.11648/j.mc.20160406.11

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Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides

Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda

Published in Modern Chemistry (Volume 4, Issue 6)

Received: 14 December 2016 Accepted: 22 December 2016 Published: 16 January 2017

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Abstract

The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.

Published in	Modern Chemistry (Volume 4, Issue 6)
DOI	10.11648/j.mc.20160406.11
Page(s)	52-58
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Isobenzofuran-Dicarboximides, Diels-Alder Reaction, Dehydration, Triflic Acid, Fluorescence

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APA Style

Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. (2017). Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Modern Chemistry, 4(6), 52-58. https://doi.org/10.11648/j.mc.20160406.11

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ACS Style

Yuki Nakahara; Haruki Shimosasa; Ryuta Miyatake; Naoki Kobayashi; Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod. Chem. 2017, 4(6), 52-58. doi: 10.11648/j.mc.20160406.11

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AMA Style

Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod Chem. 2017;4(6):52-58. doi: 10.11648/j.mc.20160406.11

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@article{10.11648/j.mc.20160406.11,
  author = {Yuki Nakahara and Haruki Shimosasa and Ryuta Miyatake and Naoki Kobayashi and Mitsunori Oda},
  title = {Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides},
  journal = {Modern Chemistry},
  volume = {4},
  number = {6},
  pages = {52-58},
  doi = {10.11648/j.mc.20160406.11},
  url = {https://doi.org/10.11648/j.mc.20160406.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20160406.11},
  abstract = {The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.},
 year = {2017}
}

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TY  - JOUR
T1  - Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides
AU  - Yuki Nakahara
AU  - Haruki Shimosasa
AU  - Ryuta Miyatake
AU  - Naoki Kobayashi
AU  - Mitsunori Oda
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N1  - https://doi.org/10.11648/j.mc.20160406.11
DO  - 10.11648/j.mc.20160406.11
T2  - Modern Chemistry
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JO  - Modern Chemistry
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PB  - Science Publishing Group
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AB  - The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.
VL  - 4
IS  - 6
ER  -

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Author Information

Yuki Nakahara

Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Haruki Shimosasa

Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Ryuta Miyatake

Centre for Environmental Conservation and Research Safety, University of Toyama, Toyama, Japan
Naoki Kobayashi

Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan
Mitsunori Oda

Department of Chemistry, Faculty of Science, Shinshu University, Matsumoto, Japan

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Plain Text BibTeX RIS

APA Style

Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. (2017). Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Modern Chemistry, 4(6), 52-58. https://doi.org/10.11648/j.mc.20160406.11

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ACS Style

Yuki Nakahara; Haruki Shimosasa; Ryuta Miyatake; Naoki Kobayashi; Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod. Chem. 2017, 4(6), 52-58. doi: 10.11648/j.mc.20160406.11

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AMA Style

Yuki Nakahara, Haruki Shimosasa, Ryuta Miyatake, Naoki Kobayashi, Mitsunori Oda. Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides. Mod Chem. 2017;4(6):52-58. doi: 10.11648/j.mc.20160406.11

Copy | Download

@article{10.11648/j.mc.20160406.11,
  author = {Yuki Nakahara and Haruki Shimosasa and Ryuta Miyatake and Naoki Kobayashi and Mitsunori Oda},
  title = {Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides},
  journal = {Modern Chemistry},
  volume = {4},
  number = {6},
  pages = {52-58},
  doi = {10.11648/j.mc.20160406.11},
  url = {https://doi.org/10.11648/j.mc.20160406.11},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.mc.20160406.11},
  abstract = {The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Synthesis and Physical Properties of Novel 7, 12-Diaryl-N-phenylbenzo[k]fluoranthene-9, 10-dicarbox- imides
AU  - Yuki Nakahara
AU  - Haruki Shimosasa
AU  - Ryuta Miyatake
AU  - Naoki Kobayashi
AU  - Mitsunori Oda
Y1  - 2017/01/16
PY  - 2017
N1  - https://doi.org/10.11648/j.mc.20160406.11
DO  - 10.11648/j.mc.20160406.11
T2  - Modern Chemistry
JF  - Modern Chemistry
JO  - Modern Chemistry
SP  - 52
EP  - 58
PB  - Science Publishing Group
SN  - 2329-180X
UR  - https://doi.org/10.11648/j.mc.20160406.11
AB  - The title arene-dicarboximides 8a–8d, having a benzo[k]fluoranthene skeleton, were synthesized in two steps from N-phenyl-1, 3-diarylisobenzofuran-5, 6-dicarboximides 4a–4d by the Diels-Alder reaction with acenaphthylene and subsequent dehydration with trifluoromethanesulfonic acid. Under photo-excitation these dicarboximides emit blue light, notably, with high quantum yields.
VL  - 4
IS  - 6
ER  -

Copy | Download